Preparation of Dispersed Platinum Nanoparticles on a Carbon Nanostructured Surface Using Supercritical Fluid Chemical Deposition

نویسندگان

  • Mineo Hiramatsu
  • Masaru Hori
چکیده

We have developed a method of forming platinum (Pt) nanoparticles using a metal organic chemical fluid deposition (MOCFD) process employing a supercritical fluid (SCF), and have demonstrated the synthesis of dispersed Pt nanoparticles on the surfaces of carbon nanowalls (CNWs), two-dimensional carbon nanostructures, and carbon nanotubes (CNTs). By using SCF-MOCFD with supercritical carbon dioxide as a solvent of metal-organic compounds, highly dispersed Pt nanoparticles of 2 nm diameter were deposited on the entire surface of CNWs and CNTs. The SCF-MOCFD process proved to be effective for the synthesis of Pt nanoparticles on the entire surface of intricate carbon nanostructures with narrow interspaces.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Preparation of Nanostructured Membranes by Reactive Depositions from Supercritical Fluids NSF Functional Nanostructures Grant 9811088

Introduction: The fabrication of structured materials for applications in optics, microelectronics, sensors, membranes, and catalysis often requires the deposition of metal or metal oxides onto or within supports or templates. Due to various fundamental constraints of deposition reactions in vapor and liquid media, current metallization techniques are typically impractical for supports with com...

متن کامل

Application of Supercritical Fluid ‎Technology for Preparation of Drug Loaded ‎Solid Lipid Nanoparticles

   Small changes in pressure or temperature, close to the critical point, lead to large changes in solubility of supercritical carbon dioxide (CO2). Environmentally friendly supercritical CO2 is the most popular and inexpensive solvent which has been used for preparation of nanodrugs and nanocarriers in drug delivery system with supercritical fluid technology. Delivery...

متن کامل

Comparison of two methods of carbon nanotube synthesis: CVD and supercritical process (A review)

A carbon nanotube (CNT) is a miniature cylindrical carbon structure that has hexagonalgraphite molecules attached at the edges. Nanotubes look like a powder or black soot, but they'reactually rolled-up sheets of graphene that form hollow strands with walls that are only one atom thick.Carbon nanotube has been one of the most actively explored materials in recent year(s) due to...

متن کامل

Chemical Fluid Deposition: Reactive Deposition of Platinum Metal from Carbon Dioxide Solution

Chemical vapor deposition (CVD) is an established, versatile technique for the preparation of high-quality metal and semiconductor thin films on solid surfaces.1,2 Despite its utility, constraints inherent to the process, including the requirement of high precursor vapor pressure and thermally coupled transport and deposition steps, generally preclude its use at low temperature and for non-line...

متن کامل

Preparation of Gd2O3 Ultrafine Nanoparticles by Pulse Electrodeposition Followed by Heat-treatment Method

Gd2O3 nanoparticles were prepared by a two–step process; cathodic electrodeposition followed by heat-treatment method. First, Gd(OH)3 nanoparticles was galvanostatically deposited from nitrate bath on the steel substrate by pulse current (PC) mode. The deposition experiments was conducted at a typical on-time and off-time (ton=1ms and toff=1ms) for 60 min. The electrodeposited precursor was the...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 3  شماره 

صفحات  -

تاریخ انتشار 2010